Temporal behavior of the SO 1.707 micron ro-vibronic emission band in Io's atmosphere

We report observations of the ro-vibronic transition of SO at 1.707 microns on Io. These data were taken while Io was eclipsed by Jupiter, on four nights between July 2000 and March 2003. We analyze these results in conjunction with a previously published night to investigate the temporal behavior of these emissions. The observations were all conducted using the near-infrared spectrometer NIRSPEC on the W.M. Keck II telescope. The integrated emitted intensity for this band varies from 0.8 x 10^27 to 2.4 x 10^27 photons/sec, with a possible link to variations in Loki's infrared brightness. The band-shapes imply rotational temperatures of 550-1000K for the emitting gas, lending further evidence to a volcanic origin for sulfur monoxide. An attempt to detect the ro-vibronic transition of SO at 0.97 microns was unsuccessful; simultaneous detection with the 1.707 micron band would permit determination of the SO column abundance.Comment: 10 pages 4 figures. Accepted by Icarus 02/27/200

Aggregate Hazes in Exoplanet Atmospheres

Photochemical hazes have been frequently used to interpret exoplanet transmission spectra that show an upward slope towards shorter wavelengths and weak molecular features. While previous studies have only considered spherical haze particles, photochemical hazes composed of hydrocarbon aggregate particles are common throughout the solar system. We use an aerosol microphysics model to investigate the effect of aggregate photochemical haze particles on transmission spectra of warm exoplanets. We find that the wavelength dependence of the optical depth of aggregate particle hazes is flatter than for spheres since aggregates grow to larger radii. As a result, while spherical haze opacity displays a scattering slope towards shorter wavelengths, aggregate haze opacity can be gray in the optical and NIR, similar to those assumed for condensate cloud decks. We further find that haze opacity increases with increasing production rate, decreasing eddy diffusivity, and increasing monomer size, though the magnitude of the latter effect is dependent on production rate and the atmospheric pressure levels probed. We generate synthetic exoplanet transmission spectra to investigate the effect of these hazes on spectral features. For high haze opacity cases, aggregate hazes lead to flat, nearly featureless spectra, while spherical hazes produce sloped spectra with clear spectral features at long wavelengths. Finally, we generate synthetic transmission spectra of GJ 1214b for aggregate and spherical hazes and compare them to space-based observations. We find that aggregate hazes can reproduce the data significantly better than spherical hazes, assuming a production rate limited by delivery of methane to the upper atmosphere.Comment: 17 figures, accepted to Ap

Seeing Double at Neptune's South Pole

Keck near-infrared images of Neptune from UT 26 July 2007 show that the cloud feature typically observed within a few degrees of Neptune's south pole had split into a pair of bright spots. A careful determination of disk center places the cloud centers at -89.07 +/- 0 .06 and -87.84 +/- 0.06 degrees planetocentric latitude. If modeled as optically thick, perfectly reflecting layers, we find the pair of features to be constrained to the troposphere, at pressures greater than 0.4 bar. By UT 28 July 2007, images with comparable resolution reveal only a single feature near the south pole. The changing morphology of these circumpolar clouds suggests they may form in a region of strong convection surrounding a Neptunian south polar vortex.Comment: 10 pages, 7 figures; accepted to Icaru

Retrieving Neptune's aerosol properties from Keck OSIRIS observations. I. Dark regions

We present and analyze three-dimensional data cubes of Neptune from the OSIRIS integral-field spectrograph on the 10-m Keck telescope, from July 2009. These data have a spatial resolution of 0.035"/pixel and spectral resolution of R~3800 in the H and K broad bands. We focus our analysis on regions of Neptune's atmosphere that are near-infrared dark- that is, free of discrete bright cloud features. We use a forward model coupled to a Markov chain Monte Carlo algorithm to retrieve properties of Neptune's aerosol structure and methane profile above ~4 bar in these near-infrared dark regions. Using a set of high signal-to-noise spectra in a cloud-free band from 2-12N, we find that Neptune's cloud opacity is dominated by a compact, optically thick cloud layer with a base near 3 bar and composed of low albedo, forward scattering particles, with an assumed characteristic size of ~1$\mu$m. Above this cloud, we require a vertically extended haze of smaller (~0.1 $\mu$m) particles, which reaches from the upper troposphere (~0.6 bar) into the stratosphere. The particles in this haze are brighter and more isotropically scattering than those in the deep cloud. When we extend our analysis to 18 cloud-free locations from 20N to 87S, we observe that the optical depth in aerosols above 0.5 bar decreases by a factor of 2-3 or more at mid- and high-southern latitudes relative to low latitudes. We also consider Neptune's methane (CH$_4$) profile, and find that our retrievals indicate a strong preference for a low methane relative humidity at pressures where methane is expected to condense. Our preferred solution at most locations is for a methane relative humidity below 10% near the tropopause in addition to methane depletion down to 2.0-2.5 bar. We tentatively identify a trend of lower CH$_4$ columns above 2.5 bar at mid- and high-southern latitudes over low latitudes.Comment: Published in Icarus: 15 September 201